TY - JOUR
T1 - Optical properties of bimetallic (SrO-K2O) nanofillers
AU - Ayeleru, Olusola Olaitan
AU - Dlova, Sisanda
AU - Ntuli, Freeman
AU - Kupolati, Williams Kehinde
AU - Olubambi, Peter Apata
N1 - Funding Information:
The National Research Foundation (NRF) is duly acknowledged for funding this study. The first author duly acknowledged Mr Stephan Wagenaar and Mr Mxolisi Nkonde, the Instrument Scientists in the Department of Applied Chemistry, University of Johannesburg for their offer of assistance to analyse the samples used in this study
Publisher Copyright:
© 2019 The Authors. Published by Elsevier Ltd.
Copyright:
Copyright 2019 Elsevier B.V., All rights reserved.
PY - 2019
Y1 - 2019
N2 - In this study, bimetallic nanofiller capable of usage as reinforcement was synthesized from expanded polystyrene (EPS). Bimetallic materials consist of two different metals. The bimetallic nanofiller consisting of SrO and K2O was successfully developed by the hydrothermal method which many researchers have well utilized to prepare nanoparticles in recent times. This study aims to synthesize and characterize bimetallic SrO-K2O, nanofillers from recycled expanded polystyrene (EPS). Products obtained were characterized by Zeta potential and Raman spectra. The Zeta potential was used to determine the surface charge of the nanofillers in solution. The Raman spectroscopy was used to determine the crystalline structure of the nanofillers. Based on the results, it was concluded that stability of nanoparticle materials in acidic medium decreases as the pH increases, and for the basic medium, stability reduces with decrease pH. The mixture of SrO and K2O to form SrO-K2O bimetallic oxide affects the stability of the nanofillers produced both in the acidic and basic medium. The Raman spectra indicated the Dband and Gband of the synthesized SrO, K2O and bimetallic SrO-K2O at 1006, 1008 and 1004 cm-1 and 1598, 1610 and 1606 cm-1 respectively. It was concluded that the shift in band gaps were because of structural changes in the molecules of the recycled expanded polystyrene.
AB - In this study, bimetallic nanofiller capable of usage as reinforcement was synthesized from expanded polystyrene (EPS). Bimetallic materials consist of two different metals. The bimetallic nanofiller consisting of SrO and K2O was successfully developed by the hydrothermal method which many researchers have well utilized to prepare nanoparticles in recent times. This study aims to synthesize and characterize bimetallic SrO-K2O, nanofillers from recycled expanded polystyrene (EPS). Products obtained were characterized by Zeta potential and Raman spectra. The Zeta potential was used to determine the surface charge of the nanofillers in solution. The Raman spectroscopy was used to determine the crystalline structure of the nanofillers. Based on the results, it was concluded that stability of nanoparticle materials in acidic medium decreases as the pH increases, and for the basic medium, stability reduces with decrease pH. The mixture of SrO and K2O to form SrO-K2O bimetallic oxide affects the stability of the nanofillers produced both in the acidic and basic medium. The Raman spectra indicated the Dband and Gband of the synthesized SrO, K2O and bimetallic SrO-K2O at 1006, 1008 and 1004 cm-1 and 1598, 1610 and 1606 cm-1 respectively. It was concluded that the shift in band gaps were because of structural changes in the molecules of the recycled expanded polystyrene.
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U2 - 10.1016/j.promfg.2019.02.068
DO - 10.1016/j.promfg.2019.02.068
M3 - Conference article
AN - SCOPUS:85067281285
SN - 2351-9789
VL - 30
SP - 483
EP - 489
JO - Procedia Manufacturing
JF - Procedia Manufacturing
T2 - 14th Global Congress on Manufacturing and Management, GCMM 2018
Y2 - 5 December 2018 through 7 December 2018
ER -