TY - JOUR
T1 - Reaction of 2-diazo-1,2-diphenylethanone with 2-[(Arylimino)methyl]phenols
AU - Pheko, Tshepo
AU - Singh, Girija S.
PY - 2006/3
Y1 - 2006/3
N2 - An equimolar reaction of the 2-diazo-1,2-diphenylethanone with 2-[(arylimino)methyl],phenols affords 2-[(arylimino)methyl]phenyl-2,2-diphenylacetates and 2-azetidinones. The products have been characterized on the basis of satisfactory spectral data. The regiochemistry of the reaction of hydroxyl and imino group towards diphenylketene, generated from thermal decomposition of the 2-diazo-1,2-diphenylethanone, has been observed to depend on the substituents on N-phenyl ring.
AB - An equimolar reaction of the 2-diazo-1,2-diphenylethanone with 2-[(arylimino)methyl],phenols affords 2-[(arylimino)methyl]phenyl-2,2-diphenylacetates and 2-azetidinones. The products have been characterized on the basis of satisfactory spectral data. The regiochemistry of the reaction of hydroxyl and imino group towards diphenylketene, generated from thermal decomposition of the 2-diazo-1,2-diphenylethanone, has been observed to depend on the substituents on N-phenyl ring.
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U2 - 10.2174/157017806775789949
DO - 10.2174/157017806775789949
M3 - Article
AN - SCOPUS:33746167746
SN - 1570-1786
VL - 3
SP - 212
EP - 213
JO - Letters in Organic Chemistry
JF - Letters in Organic Chemistry
IS - 3
ER -